Esters have gained high attention in past years due to growing demand from Alcohol production industry
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Esters |
What are esters? They are
organic compounds containing R groups derived from two different molecules -
one a carboxylic acid and another an alcohol. Because these molecules differ in
structure and properties, the name of an ester will usually reflect this. For
example, ethyl acetate gets its name from its ethyl group. Similarly, an
acetate is obtained by replacing the -ic acid in the parent acetic acid with
-ate.
A carboxylic
ester is formed by substituting a hydrogen atom in a carboxylic acid with an
organic group, usually derived from alcohol. Its general formula is RCOOR',
with the alcohol and acid names derived from the carboxylic acid and alcohol.
Examples of these include ethyl acetate and ethanoate. Other common example are
ethyl propanoate, ethyl methanoate, and ethyl propanoate.
Some wines
contain higher concentrations of them than others. It is possible for a wine to
have a higher concentration of ethyl acetate than an equivalent wine made with
a low-sulfur blend, despite its lower level of acidity. However, high-concentration
levels of these compounds may be objectionable. For example, a wine containing
more than 90 mg/L of ethyl acetate, or 200 mg/L of total esters, is considered
defective.
Esters are also highly volatile. They are used for a variety of
applications, including flavouring and solvents. Acetate one have received the
most attention in past years because they are produced at higher levels.
However, ethyl one have also been studied. The reason for this is that they
have a desirable apple-like aroma. In recent years, advances in the field of
genetics have helped identify several genes involved in ethyl ester production.
Similarly, the biochemical pathways involved in the production of
esterification make it possible to produce high-purity esters.
Esters get their
names from the parent alcohol and the parent acid, which might be organic or
inorganic. Esters generated from the simplest carboxylic acids are usually
known by "trivial names," such as formate, acetate, propionate, and
butyrate, as opposed to the IUPAC nomenclature methanoate, ethanoate,
propanoate, and butanoate. However, esters generated from more complicated
carboxylic acids are more usually termed using the systematic IUPAC
nomenclature, which is based on the name of the acid followed by the suffix
-oate. For instance, the ester hexyl octanoate, often known as hexyl caprylate,
has the formula CH3(CH2)6CO2(CH2)5CH3.
Organic esters
typically have the chemical formula RCO2R′, where R and R′ are the hydrocarbon
portions of the carboxylic acid and alcohol, respectively. Butyl acetate
(systematically butyl ethanoate), for example, might be written CH3CO2C4H9,
produced from butanol and acetic acid (systematically ethanoic acid). BuOAc and
CH3COOC4H9 are two frequent alternative presentations. Lactones are cyclic
esters, whether they are produced from an organic or inorganic acid.
-valerolactone is an example of an organic lactone.
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